期刊
ACS CATALYSIS
卷 10, 期 17, 页码 10127-10148出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c02805
关键词
amination; cross-coupling; nonprecious metal; umpolung; oxidative amination
Transition-metal-catalyzed C(sp(2))-N bond forming reactions represent a very active field of research in chemistry. This review outlines the recent developments of the first-row transition-metal-catalyzed non-Buchwald-Hartwig cross-couplings (i.e., not taking place between a (hetero)aryl (pseudo)halide and an amine or other nitrogen-containing derivatives). The oxidative and umpolung cross-couplings represent the two main types of transformations discussed in this review.
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