期刊
ACS CATALYSIS
卷 10, 期 18, 页码 10570-10576出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c03272
关键词
bismuth vanadate; trimetallic NiFeY LDH; electron density; oxygen evolution catalyst; long-term stability
资金
- National Natural Science Foundation of China [21563021, 51802320, 21872074, 21965024]
- Inner Mongolia University [21300-5195102]
- Inner Mongolia Autonomous Region [12000-15041904]
- program for Young Talents of Science and Technology in universities of Inner Mongolia Autonomous Region [NJYT-18-A01]
- Key Laboratory of Materials Processing and Mold from Zhengzhou University
In situ catalyst regeneration of NiFe-based oxygen evolution catalyst (OEC) has been recognized as one of the best approaches for photocorrosion inhibition on water splitting photoelectrodes. However, it generally suffers from laborious multistep procedures to obtain a controllable film. Herein, we use an electron density modulation to synthesize a stable NiFeY layered double hydroxide (LDH) OEC and then deposit this OEC on BiVO4 as photoanodes. The incorporation of Y modifies the chemical environment of Ni and reduces the bandgap of NiFe LDH, enhancing the electrocatalytic/photoelectrochemical performance. Importantly, Y insertion in NiFe LDH remarkably reduces the surface recombination of the BiVO4/cocatalyst system, thereby establishing a much high stability to the photocatalyst than in conventional NiFe OEC/BiVO4 approaches.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据