Inhibition of oxygen dimerization by local symmetry tuning in Li-rich layered oxides for improved stability

Li-rich layered oxide cathode materials show high capacities in lithium-ion batteries owing to the contribution of the oxygen redox reaction. However, structural accommodation of this reaction usually results in O-O dimerization, leading to oxygen release and poor electrochemical performance. In this study, we propose a new structural response mechanism inhibiting O-O dimerization for the oxygen redox reaction by tuning the local symmetry around the oxygen ions. Compared with regular Li2RuO3, the structural response of the as-prepared local-symmetry-tuned Li2RuO3 to the oxygen redox reaction involves the telescopic O-Ru-O configuration rather than O-O dimerization, which inhibits oxygen release, enabling significantly enhanced cycling stability and negligible voltage decay. This discovery of the new structural response mechanism for the oxygen redox reaction will provide a new scope for the strategy of enhancing the anionic redox stability, paving unexplored pathways toward further development of high capacity Li-rich layered oxides. Li-rich layered oxide cathodes show high capacities in Li-ion batteries but suffer from structural degradation via O-O dimerization. Here, the authors present local-symmetry-tuned Li2RuO3 with oxygen redox involving a telescopic O-Ru-O configuration avoiding O-2 release, enhancing cycling stability.