16.8% Monolithic all-perovskite triple-junction solar cells via a universal two-step solution process

Perovskite semiconductors hold a unique promise in developing multijunction solar cells with high-efficiency and low-cost. Besides design constraints to reduce optical and electrical losses, integrating several very different perovskite absorber layers in a multijunction cell imposes a great processing challenge. Here, we report a versatile two-step solution process for high-quality 1.73eV wide-, 1.57eV mid-, and 1.23eV narrow-bandgap perovskite films. Based on the development of robust and low-resistivity interconnecting layers, we achieve power conversion efficiencies of above 19% for monolithic all-perovskite tandem solar cells with limited loss of potential energy and fill factor. In a combination of 1.73eV, 1.57eV, and 1.23eV perovskite sub-cells, we further demonstrate a power conversion efficiency of 16.8% for monolithic all-perovskite triple-junction solar cells. Integrating several different perovskite absorber layers in a multi-junction solar cell imposes a great processing challenge. Here, the authors demonstrate a versatile two-step solution process for fabricating monolithic all-perovskite triple-junction solar cells.