期刊
SYNLETT
卷 32, 期 10, 页码 962-970出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1286-5934
关键词
rare-earth metal; hydrosilane; activation; catalysis; mechanism
资金
- National Natural Science Foundation of China [21890722, 22071123, 21632006]
Activation of Si-H bonds with rare-earth complexes can generate highly reactive rare-earth hydrides or silyl complexes, which are key intermediates for hydrosilylation and cross-coupling reactions. Our laboratory's recent advances in rare-earth-catalyzed hydrosilylation of unsaturated substrates and dehydrogenative coupling of hydrosilanes with amines demonstrate the unique reactivity and selectivity of rare-earth catalysts, enabling unprecedented reactions.
Activation of Si-H bonds with rare-earth complexes could generate the highly reactive rare-earth hydrides or silyl complexes, which are key intermediates for hydrosilylation and cross-coupling reactions. This Account summarizes the recent advances in the rare-earth-catalyzed hydrosilylation of unsaturated substrates and dehydrogenative coupling of hydrosilanes with amines in our laboratory. The results demonstrated that rare-earth catalysts are unique in their reactivity and selectivity, enabling some unprecedented reactions. 1 Introduction 2 Dehydrogenative Coupling of Hydrosilanes with Amines 3 Catalytic Dehydrogenative Coupling of Hydrosilanes with Amines 4 Catalytic Hydrosilylation of Terminal Alkenes and Polymerization of Styrene 5 Catalytic Hydrosilylation of Internal Alkenes 6 Catalytic Dihydrosilylation of Internal Alkynes 7 Conclusions and Outlook
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据