Historical smelting activities in Eastern Canada revealed by Pb concentrations and isotope ratios in tree rings of long-lived white cedars (Thuja occidentalis L.)

Mining activities at Duparquet in Western Quebec (Canada) have significantly affected the local environment and left behind significant amounts of metals. Monitoring this contamination is essential to infer its past and present impacts on environmental quality and to evaluate the resulting human exposure. In that context, we measured long time series of Pb concentrations and their corresponding stable isotope ratios in long-lived white cedars (Thuja occidentalis L.) growing at Duparquet Lake in order to evaluate potential time variations of the Pb environmental contamination as well as to identify the responsible source(s). Results show that before 1950, Pb at Duparquet is mostly terrigenous. Lead concentrations rapidly increase afterwards. A simultaneous shift to lower Pb-206/Pb-207 ratios identifies the smelting of Abitibi ores as the source of contamination. An isotope mass balance model evaluates at roughly 75-20%, 5-40%, 5-9% and <3% the Pb contributions from local smelters at distances of 3.6, 3.9, 7 and 9 km, respectively. The dispersion of the Pb contamination plume is possibly driven by the distance from the Beattie smelter. We finally estimated a delay of at least 13 years between atmospheric emissions from the Beattie smelting activities and the time they are recorded by tree rings. Ultimately, this study demonstrates that white cedar tree rings series provide reliable archives of past and present Pb atmospheric contamination. (C) 2020 Elsevier B.V. All rights reserved.