期刊
CRYSTENGCOMM
卷 18, 期 9, 页码 1645-1654出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce02046h
关键词
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资金
- Natural Science Funds for Distinguished Young Scholar of Heilongjiang Province [JC2015001]
- Program for New Century Excellent Talents in Heilongjiang Provincial University [1253-NCET-012]
- Natural Science Foundation of Heilongjiang Province [QC2013C008]
The correlations between properties and architecture are a central theme for electroactive materials in energy storage devices. We have conducted a systematic investigation on the relationship between the architecture and physicochemical characteristics of sulfate/C composites. Three types of carbon matrix, i.e. activated carbon (AC:0D), single wall carbon nanotubes (CNT:1D) and graphene (GA:2D) were employed to construct different structured sulfate/C composites. The discussion is focused on the relationship between the architecture and properties such as electronic conductivity, moisture absorption, sodium intercalation kinetics and the electrochemical performance of the sulfate/C composite. The Na2Fe(SO4)(2)center dot 2H(2)O/AC composite has the largest electrode/electrolyte interface and the highest porosity, thus it allows the fastest ionic diffusion and the best high-rate capability. However, the sandwich-type Na2Fe(SO4)(2)center dot 2H(2)O/GA composite has the most compact and toughest architecture, thus it allows the highest electronic conductivity and the lowest moisture sensitivity. The rational design principle for the Na2Fe(SO4)(2)center dot 2H(2)O/C composite with desirable thermodynamic and kinetic characteristics was deduced from a comprehensive evaluation of the architecture-property relationships. We also propose the electron/ion diffusion pathway and moisture absorption mechanism found for the different architectures. The present study has potential application as a design guide for Na2Fe(SO4)(2)center dot 2H(2)O/C composites in energy storage and conversion.
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