Polymer electrolytes for metal-ion batteries

The results of studies on polymer electrolytes for metal-ion batteries are analyzed and generalized. Progress in this field of research is driven by the need for solid-state batteries characterized by safety and stable operation. At present, a number of polymer electrolytes with a conductivity of at least 10(-4) S cm(-1) at 25 degrees C were synthesized. Main types of polymer electrolytes are described, viz., polymer/salt electrolytes, composite polymer electrolytes containing inorganic particles and anion acceptors, and polymer electrolytes based on cation-exchange membranes. Ion transport mechanisms and various methods for increasing the ionic conductivity in these systems are discussed. Prospects of application of polymer electrolytes in lithium- and sodium-ion batteries are outlined.