期刊
CRYSTENGCOMM
卷 18, 期 25, 页码 4799-4806出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ce00500d
关键词
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资金
- JSPS KAKENHI Grant [25420308]
- Grants-in-Aid for Scientific Research [25420308] Funding Source: KAKEN
(Y1-xGdx)(3)Al5O12:Ce ((Y,Gd)(3)Al5O12:Ce) single crystal phosphors (SCPs) were successfully grown using the Czochralski method. The Gd segregation coefficient was determined. The lattice spacing, absorption and emission properties were systematically investigated as a function of Gd concentration in a wide temperature range. Gd incorporation red-shifts the SCP emission so that neutral white with correlated color temperatures in the range of 4098-6594 K can be achieved in conjunction with a blue light-emitting diode (LED). SCPs demonstrate high conversion efficiency (> 90% above 150 degrees C) and better thermal stability compared to analogous ceramic powders. Additionally, SCPs are compatible with resin-free packaging, overcoming drawbacks associated with powder encapsulants. Therefore, (Y,Gd)(3)Al5O12:Ce SCPs are promising candidates for high-brightness neutral white sources based on intense blue LEDs and laser diodes.
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