期刊
RARE METALS
卷 40, 期 8, 页码 2254-2265出版社
NONFERROUS METALS SOC CHINA
DOI: 10.1007/s12598-020-01538-7
关键词
Magnesium; Layered double hydroxide coating; Organic inhibitors; Intercalation; Corrosion resistance
资金
- National Natural Science Foundation of China [51471021]
In this study, a Mg alloy was protected with a Mg:Al layered double hydroxide (LDH) coating intercalated with three green corrosion inhibitors, leading to improved corrosion resistance. The intercalation of corrosion inhibitors into the LDH coating was successfully achieved, and the corrosion protection mechanism was described, revealing the best-performing corrosion inhibitor.
Mg alloy was protected with Mg:Al layered double hydroxide (LDH) coating intercalated with three green corrosion inhibitors (sodium benzoate, 3-aminopropyltriethoxysilane and 8-hydroxyquinoline). The in-situ hydrothermal approach was adopted to intercalate corrosion inhibitors into Mg:Al LDH coating. The intercalated Mg:Al LDH coating was successfully acquired, and the crystalline structure of Mg:Al LDH coating was verified with X-ray diffraction (XRD). The organic functional groups of corrosion inhibitors were identified with the help of Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). The compact and uniform morphology was confirmed by scanning electron microscopy (SEM). The electrochemical measurement revealed better corrosion resistance of corrosion inhibitor-intercalated Mg:Al LDH coatings as compared to that of pristine Mg alloy. The corrosion protection mechanism of corrosion inhibitors was described and unearthed the corrosion inhibitor with the best performance.
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