4.7 Article

Rapid Synthesis of Metal-Organic Frameworks MIL-101(Cr) Without the Addition of Solvent and Hydrofluoric Acid

期刊

CRYSTAL GROWTH & DESIGN
卷 16, 期 3, 页码 1168-1171

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.5b01696

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资金

  1. Fundamental Research Funds for the Central Universities [HIT. NSRIF. 2015046]
  2. State Key Lab of Inorganic Synthesis and Preparative Chemistry, Jilin University
  3. Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry

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Metal-organic frameworks MIL-101(Cr) have been rapidly synthesized by solid-phase reaction without the addition of solvent and hydrofluoric acid at 220 degrees C, in 4 h. The obtained MIL-101(Cr) material exhibited superior catalytic activity in the oxidation of cyclohexene.

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