期刊
POWDER TECHNOLOGY
卷 378, 期 -, 页码 737-745出版社
ELSEVIER
DOI: 10.1016/j.powtec.2020.10.031
关键词
Alumina synthesis; Mesoporous alumina; Glycerol dehydration; Acrolein; Light olefins
资金
- CAPES (Brazilian Agency for Improvement of Graduate Personnel)
Mesoporous alumina was prepared by varying crystallization time and acid concentration, and evaluated in glycerol dehydration. The specific surface area, crystallinity, and acidic properties of the samples were dependent on both the crystallization time and acid concentration. The catalytic properties were related to the specific surface area and acidic characteristics, with conversions of glycerol above 92% obtained for all samples.
Mesoporous alumina was prepared by varying the crystallization time and acid concentration and evaluated in the glycerol dehydration. The samples were characterized by X-ray diffractometry (XRD), specific surface area (SBET), NH3-Temperature-programmed desorption (NH3-TPD), and Temperature-programmed Oxidation (TPO). The gas phase dehydration of glycerol was performed in a fixed-bed quartz tubular reactor at 500 degrees C using a 10% glycerol aqueous solution. The specific surface area, the crystallinity and the acidic properties of the samples were dependent on both the crystallization time and the acid concentration. The catalytic properties are related to the specific surface area and acidic characteristics. Samples with higher crystallization time showed lower surface area and lower amount of acid sites. Samples with the highest acid concentration solution had the higher surface area. Conversions of glycerol above 92% were obtained for all samples. The selectivity for dehydration products was strongly related to the amount and strength of acid sites. (C) 2020 Elsevier B.V. All rights reserved.
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