Studies on Interactions of 5,6-Diaryl-3-(Quinolin-2-YL)-1,2,4-Triazines with Arynes: A TM-Free One-Step Approach to 2-(3,4-Diarylisoquinolin-1-YL)Quinolines

Interactions of 5,6-diaryl-3-(quinolin-2-yl)-1,2,4-triazines with arynes are studied. 2-(3,4-Diarylisoqunolin-1-yl)quinolines are obtained in up to 65% yieldviathe inverse-demand Diels-Alder reaction between 5,6-diaryl-3-(quinolone-2-yl)-1,2,4-triazines and benzyne, generatedin situ.

Automated summary

The study investigates the interactions of 5,6-diaryl-3-(quinolin-2-yl)-1,2,4-triazines with arynes. 2-(3,4-Diarylisoqunolin-1-yl)quinolines are obtained in up to 65% yield through the inverse-demand Diels-Alder reaction between 5,6-diaryl-3-(quinolone-2-yl)-1,2,4-triazines and benzyne, generated in situ.