4.7 Article

Zeolitic Tetrazolate-Imidazolate Frameworks with High Chemical Stability for Selective Separation of Small Hydrocarbons

期刊

CRYSTAL GROWTH & DESIGN
卷 16, 期 6, 页码 3063-3066

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AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.6b00422

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资金

  1. 973 Program [2012CB821705]
  2. NSFC [21425102, 21573236, 21521061]
  3. Chunmiao Project of Haixi Institute of Chinese Academy of Sciences [CMZX-2015-001]

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Presented here are two zeolitic tetrazolate-imidazolate frameworks (ZTIFs) with SOD and cag topologies (ZTIF-6 and -7) directed by link-link interaction. Furthermore, the SOD-type ZTIF-6 shows high chemical stability and permanent poiosity, as well as selective separation of C2 hydrocarbons over C1 methane.

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