期刊
ORGANIC LETTERS
卷 22, 期 21, 页码 8613-8617出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c03185
关键词
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资金
- National Natural Science Foundation of China [21877055, 21762024]
- Natural Science Foundation of Jiangxi Province [20161ACB20005, 20171BCB23036, 20171BAB203008]
- Innovative Fund of Jiangxi Province [YC2018-S181]
With glycosyl o-alkynylbenzotes as donors, a highly efficient protocol to construct the challenging glycosidic linkages at C3-OH of C23-oxo oleanane triterpenoids is disclosed, on the basis of which different strategies for the highly efficient synthesis of QS-21 analogues with the west-wing trisaccharide of QS-21 have been established.
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