期刊
ORGANIC LETTERS
卷 22, 期 18, 页码 7187-7192出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02523
关键词
-
资金
- University of the Chinese Academy of Sciences, National Natural Science Foundation of China [21773240]
N-heterocyclic carbenes (NHCs) are well-known as ligands and organocatalysts, but there is no recognition for their catalytic role as a stabilizer through electrostatic interaction rather than electron donation. By utilizing the electrostatic interaction, we herein describe the success of a visible-light-triggered radical-radical cross-coupling of N-alkenoxypyridinium salts and NaI, giving a variety of alpha-iodo ketones. Computational studies characterize the stabilization role of NHCs.
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