期刊
ORGANIC LETTERS
卷 22, 期 17, 页码 6907-6910出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02440
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资金
- JSPS KAKENHI [17K05781]
- Grants-in-Aid for Scientific Research [17K05781] Funding Source: KAKEN
1-Methyl-1H-tetrazol-5-yl (MT) alkyl sulfones 1b, 3b, and 7b react with various unsymmetrical ketones in the presence of LiHMDS in THF at low temperature to give trisubstituted (Z)-alkenes in good yields stereoselectively (Z/E = 91:9 to 99:1). For sterically less demanding ketones, olefination using t-Bu reagents 1d and 3d generated (Z)-alkenes with higher stereoselectivity (93:7-99:1).
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