期刊
ORGANIC LETTERS
卷 22, 期 17, 页码 6879-6883出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02422
关键词
-
资金
- National Natural Science Foundation of China [21672105, 21725204, 91753124]
- Fundamental Research Funds for the Central Universities [Nankai University] [63191515, 63191318]
A versatile method for the construction of C(sp(2))-linked cyclophane peptide macrocycles via Pd-catalyzed picolinamide-directed intramolecular arylation of aryl and alkenyl C-H bonds of amino acid side chains with aryl iodides is developed. This method provides simple and efficient access to a variety of cyclophane-braced structures from readily accessible linear peptide precursors.
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