期刊
ORGANIC LETTERS
卷 22, 期 19, 页码 7460-7464出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02571
关键词
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资金
- National Natural Science Foundation of China [21901118, 21875109]
- Natural Science Foundation of Jiangsu Province [BK20190430]
- Fundamental Research Funds for the Central Universities [30919011217]
A photoredox-catalyzed alpha-C(sp(3))-H activation approach of unprotected secondary amines is reported. Such transformations provide facile access to various 1,4-dicarbonyl compounds using readily available amines and alpha,beta-unsaturated compounds as feedstocks under air conditions. The substrate scope of this method is broad, and a wide array of functional groups are tolerated.
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