期刊
ORGANIC LETTERS
卷 22, 期 18, 页码 7273-7277出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02608
关键词
-
资金
- Science and Engineering Research Board (SERB) [CRG/2018/001332]
- Council of Scientific and Industrial Research (CSIR) India
- University Grants Commission, New Delhi
The addition of lithium anion of (acetylmethylene)triphenylphosphorane to nonracemic sulfinimines was investigated. It was found that the addition proceeded with good diastereoselectivity and further reaction of the formed sulfinimidophosphorane with several aldehydes afforded the beta-sulfinamido substituted enones in good yields. The resultant enones were elaborated to the synthesis of alkaloid (+)-241D, to the formal total synthesis of (+)-preussin, and to the synthesis of aminocyclopentenol.
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