期刊
ORGANIC LETTERS
卷 22, 期 20, 页码 7797-7803出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02600
关键词
-
资金
- National Natural Science Foundation of China [21901066, 21702053]
- Hubei Provincial Department of Education project [Q20181003]
We report herein a B(C6F5)(3)-catalyzed redox-neutral beta-functionalization of pyrrolidines with isatins. Under transition-metal- and oxidant-free conditions at ambient temperature, a series of pyrrolidines bearing a functionalized exocyclic alkene are accessed in high efficiency through a borrowing hydrogen process. A simple switch to higher reaction temperature in a one-pot procedure also provides access to a diverse array of C(3)-functionalized pyrroles while liberating water and hydrogen gas as the only byproducts.
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