期刊
MICROCHEMICAL JOURNAL
卷 160, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.microc.2020.105624
关键词
Formaldehyde; Thermal desorption; Metal-organic framework; Quantitative analysis
资金
- R&D Center for Green Patrol Technologies through the R&D for Global Top Environmental Technologies - Ministry of Environment (MOE)
- National Research Foundation of Korea - Ministry of Science, ICT, & Future Planning [2016R1E1A1A01940995]
- Korea Ministry of Environment as part of The Chemical Accident Prevention Technology Development Project [2015001950001]
- Cooperative Research Program for Agriculture Science and Technology Development Rural Development Administration, Republic of Korea [PJ012521032018]
- Rural Development Administration (RDA), Republic of Korea [PJ012521032018] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The use of UiO-66 as a cold-trap medium in TD-GC/MS system shows efficient analysis of formaldehyde, while MOF-5 is more prone to breakthrough.
The suitability of a zirconium metal-organic framework (MOF: UiO-66) as a sorption medium for the cold-trap analytical system was explored for trace analysis of gaseous formaldehyde (FA) using thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS). A dual-bed cold trap containing UiO-66 (or MOF-5 (zinc MOF)) with Tenax (R) TA was prepared to run adsorption of FA at -25 degrees C and its desorption at 300 degrees C to acquire the maximum relative recovery up to 100%. The TD-GC/MS system equipped with a UiO-66 + Tenax (R) TA cold trap yielded a low method detection limit of gaseous FA (0.27 ng in 100 mL (2.17 ppb FA)) with good linearity and reproducibility. With the use of UiO-66 as a cold-trap medium for GC-MS analysis, the breakthrough of FA was not observable to a significantly extended sampling range (e.g., up to 800 mL of 1250 ppb (1143 ng)). In contrast, MOF-5 tested as a reference medium suffered from immediate (12.7%) breakthrough (at 250 mL) to restrict a maximum sampling only up to 50 mL. As such, the proposed method based on UiO-66 MOF is found as a highly efficient option to overcome the limitations of virtually all GC-based quantitation methods introduced previously for ambient FA. As such, this method can be used as an effective alternative method for high-performance liquid chromatography (HPLC)-based quantitation approach.
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