4.6 Article

Cs2InCl5(H2O): A moisture-stable defective double halide perovskite analogue with broadband emission

期刊

MATERIALS LETTERS
卷 277, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.matlet.2020.128280

关键词

Halide perovskite; Light emission; Moisture stability; Crystal structure; Optical materials and properties

资金

  1. National Natural Science Foundation of China [21777045, 61875119]
  2. Natural Science Foundation of Guangdong
  3. Shanghai Rising-Star Program [19QA1404000]
  4. U.S. Department of Energy, Office of Science, Basic Energy Sciences [DE-AC02-76SF00515]

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This study reports a moisture-stable direct bandgap defective double halide perovskite analogue constructed from [InCl5(H2O)](2-) octahedra. The introduction of heterogeneous oxygen in the octahedra position is crucial for achieving a broadband emission and for increasing the chemical and moisture stability. These unique merits make Cs2InCl5(H2O) a promising environmentally-friendly material to achieve applications for future optoelectronic devices. (C) 2020 Elsevier B.V. All rights reserved.

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