期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 41, 期 19, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000369
关键词
crosslinking; photochemistry; photopolymerization
资金
- Istanbul Technical University Research Fund
- Council of Higher Education (YOK)
- Scientific and Technological Research Council of Turkey (TUBITAK)
It is herein reported that a facile application ofN-acyl dibenzazepine (ADBA) photochemistry for preparing photoreversible ADBA based thiol-ene networks. Crosslinking of the ADBA thiol-ene networks is successfully achieved by UV induced dimerization of ADBA groups at wavelengths above 300 nm while a subsequent deep UV exposure (lambda = 250 nm) results in a well-defined cleavage of the crosslinks. The photochemical bonding and cleavage of the process has been determined and studied in detail by spectroscopic measurements.
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