期刊
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
卷 113, 期 -, 页码 315-324出版社
ELSEVIER
DOI: 10.1016/j.jtice.2020.08.037
关键词
Coordination polymer; Selective adsorption; Hg(ii)Pb(ii); Mechanism
资金
- Hubei Provincial Department of Education Science and Technology Research Program Young Talent Project [Q2020113]
- National Natural Science Foundation of China [U1702252, 51864042, 51804220]
At present, the functionalized Zr-based coordination polymer for heavy metal ions removal are primarily implemented via post-synthesis, and it is still a challenge to reduce the concentration of heavy metal ions to wastewater discharge standard. In this work, the 2,2'-dithiodipropionic acid modified Zr-based coordination polymer (named as Zr-DTDPA) was prepared by direct synthesis. It presented extraordinary adsorption ability in the process of removing Hg(II)/Pb(II). The optimum pH for Hg(II) and Pb(II) absorption was 4.0 and 6.0, respectively, and the saturated adsorption capacity reached 960 mg/g and 478 mg/g. The adsorption process can be exceedingly fitted by Langmuir isotherm model and pseudo-second-order (PSO) kinetic model, which indicated that chemisorption played a dominant role. Additionally, the maximum selectivity coefficient reached 21.36 x 10(5) and 5605 for Hg(II) and Pb(II). Impressively, the residual contents of Hg(II) and Pb(II) were only 1.04 mu g/L and 0.34 mg/L, which respectively reached the concentration standard of Hg(II) and Pb (II) in wastewater. Zr-DTDPA was easy to be regenerated, and the removal rate of Hg(II) had only decreased by 17.15% after ten consecutive cycles. The results of Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) suggested that the adsorption performance of Zr-DTDPA toward Hg (II)/Pb(II) was primarily determined by thiol/thio groups, and the adsorption mechanism was the interaction between sulfur atoms and Hg(II)/Pb(II) ions. (C) 2020 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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