期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 42, 页码 17908-17912出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c08450
关键词
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资金
- TopSector HighTech Systems & Materials in the TKI project Early cancer diagnostics
- CNRS
- Agence Nationale de la Recherche [ANR-17-CE09-0034-01]
Faradaic reactions at low supporting electrolyte concentrations induce convection via electroosmotic flows. Here we combine finite-element simulations and electrochemical measurements on microparticles at ultramicroelectrodes to explore this effect. We show that convection becomes the dominant form of mass transport for experiments at low salt concentrations, violating the common assumption that convection can be neglected.
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