期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 104, 期 1, 页码 183-207出版社
WILEY
DOI: 10.1111/jace.17447
关键词
aluminosilicates; borosilicate glass; international simple glass; molecular dynamics; nuclear magnetic resonance; scattering
资金
- Office of Science [DE-SC0016584]
- Nuclear Energy University Programs [DE-NE0008694]
- U.S. Department of Energy (DOE) [DE-SC0016584] Funding Source: U.S. Department of Energy (DOE)
This study aims to understand the detailed structural changes caused by Al:Si and (Al + Na):Si substitutions in nuclear waste glasses, by combining experimental structural characterizations and molecular dynamics simulations. The research provides insights on the structural origins of property changes in glasses caused by substitutions, laying a foundation for future improvements in theoretical and computer simulation models.
High-alumina containing high-level waste (HLW) will be vitrified at the Waste Treatment Plant at the Hanford Site. The resulting glasses, high in alumina, will have distinct composition-structure-property (C-S-P) relationships compared to previously studied HLW glasses. These C-S-P relationships determine the processability and product durability of glasses and therefore must be understood. The main purpose of this study is to understand the detailed structural changes caused by Al:Si and (Al + Na):Si substitutions in a simplified nuclear waste model glass (ISG, international simple glass) by combining experimental structural characterizations and molecular dynamics (MD) simulations. The structures of these two series of glasses were characterized by neutron total scattering and(27)Al,Na-23,Si-29, and(11)B solid-state nuclear magnetic resonance (NMR) spectroscopy. Additionally, MD simulations were used to generate atomistic structural models of the borosilicate glasses and simulation results were validated by the experimental structural data. Short-range (eg, bond distance, coordination number, etc) and medium-range (eg, oxygen speciation, network connectivity, polyhedral linkages) structural features of the borosilicate glasses were systematically investigated as a function of the degree of substitution. The results show that bond distance and coordination number of the cation-oxygen pairs are relatively insensitive to Al:Si and (Al + Na):Si substitutions with the exception of the B-O pair. Additionally, the Al:Si substitution results in an increase in tri-bridging oxygen species, whereas (Al + Na):Si substitution creates nonbridging oxygen species. Charge compensator preferences were found for Si-[NBO] (Na+),B-[3]-[NBO] (Na+),B-[4] (mostly Ca2+),Al-[4] (nearly equally split Na(+)and Ca2+), and([6])Zr (mostly Ca2+). The network former-BO-network former linkages preferences were also tabulated; Si-O-Al and Al-O-Al were preferred at the expense of lower Si-O-B-[3] and([3])B-O-B-[3] linkages. These results provide insights on the structural origins of property changes such as glass-transition temperature caused by the substitutions, providing a basis for future improvements of theoretical and computer simulation models.
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