期刊
JOURNAL OF POWER SOURCES
卷 469, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2020.228425
关键词
Supercapacitor; Flexible electrode; TiO2 nanowires; MnO2 nanosheets; Carbon cloth; Potential window
资金
- Natural Science Foundation of Zhejiang Province [LY20E020013]
- National Natural Science Foundation of China [51862005]
Flexible supercapacitors with aqueous electrolytes are attractive safe power sources; yet low specific capacitance and narrow operating voltage hinder their practical applications. Herein, we deposit arrays of TiO2 nanowires (TiO2@CC) and MnO2 nanosheets (MnO2@CC) on carbon cloth via a solution-based technique at 80 degrees C and in an open atmosphere. The TiO2 nanowires possess intrinsic low hydrogen evolution reaction activities and in turn a wide working window (-1.6-0 V vs. Hg/HgO). The high specific surface area and favorable pore texture endow the TiO2@CC and the MnO2@CC with high areal specific capacitances of 1204.8 mF cm(-2) and 1427.2 mF cm(-2), respectively. A 2.6 V wide potential window aqueous asymmetric supercapacitor is then constructed, which exhibits an exceptional high specific capacitance of 1010.8 mF cm(-2), high volumetric energy density of 4.75 mW h cm(-3) and volumetric power density of 325 mW cm(-3). The areal energy density and areal power density are 0.949 mW h cm(-2) and 65 mW cm(-2), respectively. The excellent cyclic stability of 100% capacity retention after 50,000 cycles at a high current density of 5 mA cm(-2) is recorded and the supercapacitor also exhibits good flexibility.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据