期刊
JOURNAL OF POWER SOURCES
卷 472, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2020.228610
关键词
CO2 capture; Supercapacitor; Graphene; Nitrogen doping; Porous carbon
资金
- National Natural Science Foundation of China, China [21676169, 21978182]
- China Petroleum and Chemical Corporation [416050]
A novel hierarchical porous carbon derived from poly(p-phenylenediamine) incorporated with reduced graphene oxide (rGO) is prepared for CO2 capture and supercapacitors. In this synthesis, chemically in-situ oxidative polymerization and KOH chemical activation are employed with the controllable introduction of GO (GO/Polyphenylenediamine = 0-2 wt%). The obtained carbon material (APG-1%) with high surface area (860.4 m(2) g(-1)) and rich N content (7.91 wt%) exhibits excellent CO2 capture ability (4.65 mmol g(-1) at 298 K, 5 bar) and good electrochemical performance as a supercapacitor electrode with 158.5 F g(-1) in 6 M KOH at a current density of 1 A g(-1). Even at a high current density of 10 A g(-1), a capacity of 115.2 F g(-1) is still maintained. The rational addition of rGO provides an effective strategy of simultaneous improvement of CO2 adsorption and capacitive performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据