期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 923, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2020.121353
关键词
Palladium; Micellar; Water/ethanol; Recycling; Suzuki-miyaura
资金
- Spanish Ministerio de Ciencia, Innovacion y Universidades [CTQ2016-76782-P, CTQ2016-81797-REDC CTQ2016-81893REDT, RED2018-102387-T]
- Spanish Ministerio de Economia, Industria y Competitividad, Agencia Estatal de Investigacion (AEI)
- Fondo Europeo de Desarrollo Regional (FEDER, EU) [CTQ2016-76782-P]
- Generalitat Valenciana [PROMETEOII/2014/017]
- USTO-MB
- Universities of Mersin and Alicante
The Suzuki-Miyaura cross-coupling reaction using 4-amino-1,2,4-triazoles and 1,3,4-oxadiazoles-2-thiones center dot palladium (II) is studied. The reaction is optimized and the most appropriate catalytic complex is tested with several aryl halides, boronic acids in an environmentally benign solvent system (H2O/EtOH). The recovery of the catalytic species is also surveyed because of the nature of the employed solvent. A domino process is efficiently carried out following the standard conditions. Several surface parameters of the ligands are analyzed and the resulting values are extrapolated to the insoluble palladium catalyst. (C) 2020 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据