期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 20, 页码 13272-13279出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c01670
关键词
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资金
- SERB [EMR/2017/005028]
- CAS-V
- DST-FIST at the Department of Chemistry, CU, India
A metal-free, simultaneous triple C-C coupling cyclization reaction between phenacyl bromides and indoles is discovered in a highly regioselective fashion to furnish 3,5-diarylcarbazoles. DMAP is utilized as the only reagent for the unusual and rapid cyclization reaction to furnish all new carbazole compounds through installation of a great diversity of substituents. A plausible radical mechanism for the new reaction is predicted by conducting various control experiments, competitive reactions, furoindole formation, and ESI-MS analyses of the ongoing cyclization reaction.
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