期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 19, 页码 12740-12746出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00823
关键词
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资金
- NIGMS-NIH [1R15GM126498-01]
- NSF MRI program [CHE:1726931]
- Northern Illinois University
The conjugate addition reactions of trans-1,2-di(2-pyridyl)ethylene have been studied. This substrate reacts with organolithium nucleophiles, and the resulting anionic intermediates may be trapped by proton or various carbonyl-based electrophiles. It is suggested that the dipyridyl structure stabilizes the intermediate carbanion, allowing the Michael adduct to be captured by an added electrophile.
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