期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 18, 页码 11989-11996出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c01818
关键词
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资金
- National Natural Science Foundation of China [21576296, 21776318, 21676302, 81703365]
- Fundamental Research Funds for Central South University [2019zzts222, 2020zzts401]
- Central South University
Acyl oximes are directly used as the acyl radical precursors in the hydroacylation reactions for the first time. In this work, acyl radicals can be effectively generated via beta-scission of a phosphoranyl radical under photocatalytic conditions. As a result, the hydroacylation of alkenes triggered by the resulting acyl radicals leads to facile syntheses of a range of valuable ketones.
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