期刊
COORDINATION CHEMISTRY REVIEWS
卷 309, 期 -, 页码 84-106出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.10.004
关键词
Polyoxometalate; Hybrid inorganic-organic; Crystal engineering; Flexible ligands; Entangled structures; Charges
资金
- Ferdowsi University of Mashhad [28396/3-2013/10/02]
- MINECO of Spain (project CONSOLIDER INGENIO) [CSD2010-00065, CTQ2014-57393-C2-1-P]
- MINECO of Spain (project FEDER funds)
Currently, the design and assembly of hybrid inorganic-organic compounds has become an area of rapid growth due to their structural diversities as molecular building blocks. Polyoxometalates (POMs) as a subset of metal oxides, that represent a tremendous range of inorganic clusters with unique physical and chemical performances, possess intriguing structures and abundant potential applications. In the self assembling process of POM-based architectures, in addition to the important role of POMs, the choice of adequate ligands is significant to modulate the properties of inorganic-organic hybrids. Moreover, flexible N-donor ligands, including imidazole, triazole, tetrazole, and pyridyl derivatives with strong coordination capacity have been used for construction of POM-based compounds with attractive topologies and different dimensionality. Thus, this review puts into perspective latest research on this topic focusing to the construction of hybrid inorganic-organic materials based on flexible ligands. Remarkably, they provide to POM-based systems the flexibility and conformational freedom necessary to satisfy the coordination environment of the metal centers creating fascinating structural topologies, such as entangled and other structures with various architectures. In addition, this review also describes recent work devoted to analyze how the negative charge of POMs influences the supramolecular assembly of hybrid inorganic-organic compounds. (C) 2015 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据