期刊
JOURNAL OF NATURAL MEDICINES
卷 75, 期 1, 页码 99-104出版社
SPRINGER JAPAN KK
DOI: 10.1007/s11418-020-01457-y
关键词
Acacia mangium; Terpenoid-like C20 natural product; Androsterone-like cyclopentenone moiety; Bangladesh plant
资金
- KAKENHI from the Japan Society for the Promotion of Science [20H03394, 20K16024]
- Grants-in-Aid for Scientific Research [20H03394, 20K16024] Funding Source: KAKEN
Acacienone (1), a novel C20 natural product, was isolated from the leaves of Acacia mangium collected in Bangladesh. The compound's structure was determined by spectral studies and X-ray crystallographic analysis, revealing unique terpenoid-related features.
A novel C20 natural product, acacienone (1), was isolated from the leaves ofAcacia mangiumcollected in Bangladesh. The structure of compound1was elucidated by spectral studies and X-ray crystallographic analysis. Acacienone (1) possesses a terpenoid-related tetracyclic framework containing 20 carbons with biogenetically unusual structural features: (i) vicinal C1-branches at the C-3 and C-4 positions in the A ring, and (ii) a cyclopentenone D ring in an androsterone-like assembly, lacking a methyl group at the C-13 position.
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