期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1217, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2020.128395
关键词
Fluorene compounds; Synthesis; Fluorescence sensor; L-argnine
资金
- Basic Natural Science Research, China Project of Liaoning Education Department [LJ2019008]
Two compounds, 4-(4-(7-bromo-9, 9-dimethyl-fluoren-2-yl) phenyl) pyridine (4) and 2, 7-Bis-(4-tert-butyl-phenyl)-9,9-dimethyl-9H-fluorene (5) , were synthesized by bromination, methylation and Suzuki coupling reaction with fluorene as the starting material. The compounds were used as fluorescent sensors to detect some nitro compounds (NACs), metal cations and amino acids. The test results showed that the 4-(4-(7-bromo-9, 9-dimethyl-fluoren-2-yl) phenyl) pyridine (4) as fluorescence sensor 1 detected 2, 4, 6-Trinitrophenol (TNP) at the magnitude of 10 mM, with a sensitivity of K sv was 4.6 x 10(5) M-1 and the detection limit was 6.9 x 10(-7) M. The sensitivity detection for Fe3+ with K sv value was 1.4 x 10(5) M-1 , and the detection limit was 3.6 x 10(-7) M. At the same time, it was found that 2, 7-Bis-(4-tert-butyl-phenyl)-9,9-dimethyl-9H-fluorene (5) as fluorescence sensor 2 also showed excellent se-lective recognition ability toward the arginine (L-arg) in biomolecules with K sv values of 3.9 x 10(4) M-1 , and the detection limit was 1.15 x 10(-6) M for arginine (L-arg). (C) 2020 Elsevier B.V. All rights reserved.
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