Effect of bismuth (Bi3+) substitution on structural, optical, dielectric and magnetic nature of La2CoMnO6double perovskite

Double perovskite oxide materials represented as A(2)BB ' O(6)have attracted a great attention due to their diverse electrical, magnetic and structural properties. In this report, we discuss synthesis, structural, optical, magnetic and electric nature of the double perovskite manganites of the type La2-xBixCoMnO6[x = 0.0, 0.1, 0.2]. These solid-state reaction route products withx = 0.0, 0.1 were found monoclinic structured (P 1 21 / n 1) confirmed from the X-ray diffraction data analysis, whereas the sample withx = 0.2 has acquired a new structure confirmed to be cubic (Fm-3 m) with another phase corresponding to Bi(2)O(3)crystallized in monoclinic structure acquiring space groups P 1 21 / c 1. The results of XRD data analysis were re-verified via Rietveld refinement. The phase formation was further verified via Raman and FTIR spectral studies. The samples were investigated for composition and morphology also. The optical bandgap was determined (approximate to 1 eV) from the diffuse reflectance UV-Vis spectra. Temperature-dependent dielectric constant and dielectric loss was investigated in the temperature range of 320-90 K at various constant values of appliedacfield and the results were exceptionally good. Electrical (dc) resistivity exploiting four-probe technique with and without magnetic field infer the samples are semiconducting in nature. Room temperature magnetic measurement reveals the samples exhibit low magnetic moment which shows linear behaviour in both forward and reverse field values.

Automated summary

The report discusses the synthesis, structure, optical, magnetic, and electric properties of double perovskite manganites La2-xBixCoMnO6[x = 0.0, 0.1, 0.2]. The XRD, Raman, and FTIR analyses confirm the crystal structures, while electrical resistivity tests indicate semiconducting behavior. Room temperature magnetic measurements show low magnetic moment with linear behavior.