Low pressure operated ultrafiltration membrane with integration of hollow mesoporous carbon nanospheres for effective removal of micropollutants

An effective way to remove micropollutants is desirable for water purification. In this work, a dual-functional ultrafiltration (DFUF) membrane was fabricated by loading hollow mesoporous carbon nanospheres (HMCNs) into the finger-like support layer pores of the polymeric ultrafiltration (UF) membrane. The designed DFUF membrane combines the high selectivity of ultrafiltration that removes macromolecules based on size exclusion mechanism, and excellent adsorption capacity of HMCNs towards micropollutants in water. When tetracycline (TCN) and 17 beta-Estradiol (E2) were selected as model micropollutants, corresponding 97 % and 94 % removal were achieved at a low pressure less than 0.15 bar and a flux of 50 and 64 L h(-1) m(-2) (estimated residence time less than 6 s), respectively. Moreover, simultaneous removal of multiple pollutants was demonstrated by filtering a mixture containing TCN and polyethylene glycols (PEG) 600 kDa macromolecules. Over a long filtration period (more than 60 h) that produced 3180 L/m(2) of permeate, the TCN concentration reduced from 100 mu g/L in the feed to less than 10 mu g/L in the permeate. The above results indicate that the DFUF membrane is capable of removing the small molecular and macromolecular pollutants simultaneously at low pressure, and hence offers remarkable potential in water treatment applications.