期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 575, 期 -, 页码 480-488出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2020.05.016
关键词
Oil-in-water HIPEs; Amphoteric polyelectrolyte; Quenched polyampholytes; Poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS); Poly(3-acrylamidopropyl)trimethylammonium chloride (PAMPTMA)
资金
- Ministry of Education, Science and Technology of the Republic of Slovenia
- Slovenian Research Agency [P20145]
- Austrian Science Fund (FWF) [P20145] Funding Source: Austrian Science Fund (FWF)
Hypothesis: Macroporous polyampholyte hydrogels, simultaneously bearing both the anionic and cationic groups, demonstrate immense promise over the one-sign charged polyelectrolytes, owing to a unique phenomenon known as the}anti-polyelectrolyte} effect. Thus, they are extremely promising materials, since they remain solvated and functional even in harsh conditions. Furthermore, macroporous morphology significantly enhances polyampholyte response to external stimuli, since it accelerates the solvent transport through the hydrogel. Experiments: A new templated-synthesis through ''HIPE mixtures is reported, where the two pre-formed high internal phase emulsions (HIPE) containing the oppositely charged monomers (2-acrylamido-2-m ethyl-1-propanesulfonic acid and (3-acrylamidopropyl)trimethylammonium chloride) were combined in the same mould, which after polymerization result in the formation of macroporous monoliths of different structures. The resulting frameworks were either copolymer or dual homopolymers in the form of bilayered or mixed porous structures. Findings: The co- and mixed-amphoteric polyelectrolytes exhibit 'anti-polyelectrolyte' behaviour typical of polyampholytes, while the bilayered-structure behaves like a typical polyelectrolyte. Complete and simultaneous removal of both dyes from a dye mixture was observed for the bilayered- and mixed-amphoteric polyelectrolyte, while copoly-ampholyte showed only partial dye adsorption. These results clearly reveal the benefits of a mutual combination of the HIPE-templated structure and the oppositely charged amphoteric nature in one-piece material as a promising avenue toward advanced materials. (C) 2020 Elsevier Inc. All rights reserved.
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