期刊
JOURNAL OF CATALYSIS
卷 389, 期 -, 页码 345-351出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2020.06.006
关键词
Water splitting; Electrocatalysis; Polyoxometalates; Cobalt
资金
- FEDER/Ministerio de Ciencia, Innovacion y Universidades -Agencia Estatal de Investigacion [RTI2018-095618-B-100, CTQ2017-87269-P]
- Generalitat de Catalunya [2017-SGR-797, 2017-SGR-629]
- Generalitat de Catalunya (CERCA program)
- MINECO
- US-Spain Fulbright Committee
- FEDER
- FSE
A series of Cobalt-polyoxometalates (Co-POM) have been incorporated into carbon paste electrodes as insoluble salts of Cs+ or Ba2+. Specifically, we included the lacunary Keggin-type derivatives [Co(H2O)(PW11O39)](5-) (CoPW11), [Co(H2O)(SiW11O39)](6-) (CoSiW11), [Co(H-2)(CoW11O39)](7-) (CoCoW11), [Co-4(H2O)(2)(PW9O34)(2)](1)(0-) (Co4P2W18), [Co-4(H2O)(2)(SiW9O34)(2)](1)(2-) (CO4Si2W18), and [Co-9(H2O)(6)(OH)(3) (HPO4)(2)(PW9O34)(3)](16-) (Co-9); and the lacunary Dawson-Wells derivative [Co-4(H2O)(2)(P2W15O56)(2)](16)(-)(Co4P4W30). The activity and stability of these composite electrodes towards water oxidation in acidic media (pH < 1) was examined by electrochemical methods and post-catalytic characterization. Our results indicate the stability of these catalysts in these conditions depends on composition, since only those species containing P-V as heteroatom appeared to be stable. All Si-IV and Co(III)( )derivates showed rapid decomposition, regardless their nuclearity or molecular structure. All stable derivatives exhibited consistent activity, favored by high nuclearity and overall total charge, with Keggin derivatives being intrinsically more active than the corresponding Dawson-Wells analogues. (C) 2020 Published by Elsevier Inc.
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