期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 857, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157581
关键词
Lithium ion battery; Cathode; Recycling; Aluminum; Rate capability
资金
- National Research Foundation of Korea (NRF) - Ministry of Education [2020R1A6A1A03038540]
- Ministry of Science and ICT [2020R1F1A1053911]
- Korea Ministry of Environment (MOE)
- National Research Foundation of Korea [2020R1F1A1053911] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The study synthesized cathode active materials with varying Al content and examined the effects on physicochemical, thermal, and electrochemical properties. Results showed that increased Al content in the materials led to irregular particle shape and distribution, reduced initial charge/discharge capacity and cyclability, but improved rate capability. Residual Al was found to adversely affect capacity and cyclability, suggesting that trace amounts of Al in the materials can be tolerated.
As the demand for various electronic devices using the advantages of lithium ion batteries (LIBs) increases, the disposal of LIBs has also been an important issue. We synthesize Li[Ni1/3Mn1/3Co1/3]O-2 (NMC) and Li[Ni1/3Mn1/3Co1/3]AlxO2,(NMCA) cathode active materials with various amounts of Al (NMCA (x%)) via hydroxide coprecipitation and calcination processes, which simulates the resynthesis of NMC in leachate containing Al from spent LIBs. The effects of Al on the physicochemical, thermal and electrochemical (initial charge/discharge capacity, cyclability and rate capability) properties of NMCA are investigated and compared with NMC. An increase in the Al content in NMCA incurs an irregular shape and the uneven distribution of active material particles as confirmed by scanning electron microscope. The initial charge/discharge capacity and cyclability deteriorate as the Al content increases. The capacity retention of NMCA (2.00%) starts to decline rapidly at an earlier cycle than the other NMCA samples. On the other hand, the rate capability of NMCA is enhanced and electrochemical impedance spectroscopy analysis shows that NMCA (2.00%) has a higher lithium ion diffusion coefficient than NMC. Overall, residual Al in the cathode active materials has an adverse effect on capacity and cyclability, which could be tolerated with traces of Al less than 0.05% in NMCA. (C) 2020 Elsevier B.V. All rights reserved.
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