期刊
IONICS
卷 26, 期 12, 页码 6057-6067出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11581-020-03755-7
关键词
Lithium-ion battery; Separator; Ceramic fiber paper; High safety
资金
- National Natural Science Foundation of China [51472144, 51372140]
- Shandong University Young Scholars Program [2016WLJH27]
- Fundamental Research Funds for the Central Universities [2082019014]
The non-woven mat has a three-dimensionally distributed fiber structure, but because the randomly dispersed structure caused the pore diameter of the separator to enlarge, this may lead to a short circuit of the battery. In this work, organic polyethylene terephthalate (PET) was combined with inorganic zirconia (ZrO2) ceramic fiber using a low-cost papermaking method. The addition of PET blocked part of the macropores of the fiber separator, enabling the separator a suitable pore size. The PET connected the nodes of the zirconia fibers to provide mechanical support. At the same time, the ZrO2-PET composite separator inherited the excellent high temperature resistance of zirconia ceramic fiber and a maintained dimensional stability after heating at 300 degrees C for 1 h, providing a strong guarantee for the safe performance of the battery. We found that when the concentration of PET was 5%, the highest electrolyte uptake (301.83%) occurred as well as electrochemical performance. In addition, the ZrO2-PET composite separator achieved an excellent cycle performance at 60 degrees C compared with the polypropylene (PP) separator.
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