期刊
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
卷 158, 期 -, 页码 420-429出版社
ELSEVIER
DOI: 10.1016/j.ijbiomac.2020.04.259
关键词
Polysaccharide; Thermomechanical processing; Polyelectrolyte complexation; Graphene oxide; Microstructure; Contact angle
资金
- European Union's Horizon 2020 - Research and Innovation Framework Programme under the Marie Sklodowska-Curie grant [798225]
- China Scholarship Council (CSC)
- Guangxi Key Laboratory for Polysaccharide Materials and Modification, Guangxi University for Nationalities, China [GXPSMM18ZD-02]
Bionanocomposites of chitosan and chitosan/carboxymethyl cellulose (CMC) polyelectrolyte complexed mate-rials with graphene oxide (GO) or reduced graphene oxide (rGO) were prepared by thermomechanical process -ing with excellent levels of dispersion. While GO has a greater affinity with the chitosan polycation, rGO had a more pronounced effect on properties resulting in increased tensile strength, Shore D hardness, and thermal sta-bility of both matrices. Although GO is more hydrophilic than rGO, the former increased more effectively the sur -face hydrophobicity of the biocomposites regardless of matrix type. GO and rGO changed the alpha-transition of the biocomposites in a similar manner. The electrochemical properties of the biocomposites were influenced by both nanofiller type and matrix. This research revealed that inclusion of 2D carbon nanomaterials can alter biopolymer interactions and that the phase structure of the biopolymer blend may play a more important role than nanofiller-matrix interactions in determining the overall properties of these bionanocomposites. (C) 2020 Elsevier B.V. All rights reserved.
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