Eu(III)-organic framework as a multi-responsive photoluminescence sensor for efficient detection of 1-naphthol, Fe3+ and MnO4- in water

A new three-dimensional Eu(III) metal-organic framework Eu(III)-MOF-1 formulated as [Eu-3(BDC)(4.5)(H2O) (DMF)(2)] (H2BDC = 1,4-benzenedicarboxylic acid), has been successfully synthesized by solvothermal methods and characterized by structural analyses and luminescence studies. Crystallographic studies reveal that the Eu-MOF-1 exhibits an unusual 3D framework based on 1D metal-carboxylate chains. Significantly, the luminescence explorations demonstrate that the Eu-MOF-1 is the first multi-responsive fluorescence sensor for sensing bio-marker 1-naphthol (1-N) of carbaryl exposure, Fe3+ ions and MnO4- ions with high sensitivity, selectivity and excellent recyclability through luminescence quenching. Moreover, the possible mechanisms of selective de-tection have been investigated in detail. This material could be a promising luminescent sensor for practical applications.