期刊
INORGANIC CHEMISTRY
卷 59, 期 17, 页码 11915-11919出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c01752
关键词
-
资金
- National Natural Science Foundation of China [21801139, 21871227]
- Natural Science Foundation of Jiangsu Province [BK20180942]
- Natural Science Foundation of Nantong City [JC2019087]
- project of Six Talent Peaks in Jiangsu Province [XCL085]
- project of Jiangsu Association for Science and Technology Young Science and Technology Talents Lifting
Mechanically interlocked molecules are a class of smart supramolecular species because of their interesting topological structure and application in various areas, such as biology and nanoscience. In this work, we used multicomponent reaction to fabricate a new [2]rotaxane based on pillar[5]arene from different small-sized molecules. The molecular structure of the obtained [2]rotaxane R was confirmed by H-1 and C-13 NMR, high-resolution electrospray ionization mass spectrometry, two-dimensional nuclear Overhauser effect spectroscopy, and density functional theory studies. Interestingly, the [2]rotaxane-based organometallic cross-linked catalyst (Pd@R) was easily constructed via the coordination between triazole groups and Pd(NO3)(2). Pd@R proved to be a good catalyst for the Suzuki-Miyaura coupling reaction with excellent stability and repeatability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据