期刊
ENVIRONMENTAL POLLUTION
卷 264, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2020.114696
关键词
Antimony; Microplastics; Contamination; Deposit-feeders; Bioaccessibility; Kinetics
Antimony (Sb) widely occurs in plastics as a pigment and reaction residue and through the use and recycling of electronic material enriched in Sb as a flame retardant synergist. In this study, clean estuarine sediment has been contaminated by different microplastics prepared from pre-characterised samples of different types of plastic (including a rubber) containing a range of Sb concentrations (256-47,600 mu g g(-1)). Sediment-plastic mixtures in a mass ratio of 100:1 were subject to 6-h extractions in seawater and in seawater solutions of a protein (bovine serum albumin; BSA) and a surfactant (taurocholic acid; TA) that mimic the digestive conditions of coastal deposit-feeding invertebrates. Most timecourses for Sb mobilisation could be defined by a second-order diffusion equation, with rate constants ranging from 44.6 to 0.0216 (mu g g(-1))(-1) min(-1). Bioaccessibilities, defined as maximum extractable concentrations throughout each time course relative to total Sb content, ranged from <0.01% for a polycarbonate impregnated with Sb as a synergist exposed to all solutions, to >1% for acrylonitrile butadiene styrene containing a Sb-based colour pigment exposed to solutions of BSA and TA and recycled industrial polyethylene exposed to BSA solution. The potential for Sb to bioaccumulate or elicit a toxic effect is unknown but it is predicted that communities of deposit-feeders could mobilise significant quantities of Sb in sediment contaminated by microplastics through bioturbation and digestion. (C) 2020 Elsevier Ltd. All rights reserved.
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