Advances in application of cotton-based adsorbents for heavy metals trapping, surface modifications and future perspectives

Cotton-based adsorbents (CBAs) are promising materials for combating the problem of heavy metal pollution of environmental waters. This is ascribed to the low cost, abundance, biodegradability and efficiency of CBAs. Herein we review the adsorption of heavy metals (HMs) onto CBAs. We found that several surface modifications were employed to improve the efficiency of the CBAs. These modifications were effected via thermal, physical and chemical means to obtain activated carbons, biochars, ionic liquids, aerogels, hydrogels, chitosans and nanoparticle-derived CBAs. The CBAs exhibited maximum HMs uptake as low as 0.002 mg/g to as high as 505.6 mg/g. Although, the cotton-derived activated carbons and biochars exhibited enhanced HM uptake from that of the unmodified CBAs, they were less efficient than CBAs modified by other methods. Recent chemical, ionic liquid, chitosan and nano-derived CBAs were the most efficient, with high uptake and fast kinetic removal. However, the nanoparticle-based adsorbents are preferred to the chemically modified forms, due to the possibility of secondary pollution and the noxious effect of the later to the environment. Findings showed that chemical treatment produced CBAs most efficient for As(V), Pb(II) and Fe(III), while ionic liquid CBA was more efficient for Cu(II) and Ni(II). Nano-based treatment was suitable for the uptake of Co(II), Zn(II), Pb(II) and Cd (II), while the chitosan based adsorbent was viable for Hg(II). Isotherm and kinetic evaluation of CBAs mostly conformed to the Langmuir and pseudo-second order models, respectively. Spontaneous adsorption of HMs onto CBAs was deduced from thermodynamic analysis, with endothermic and exothermic characteristics. Over 88% desorption of HMs was obtained from the CBAs studied with good average reusability from 3 to 20 cycles. We also discussed the directions for future research.