期刊
CORROSION SCIENCE
卷 175, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2020.108884
关键词
Stainless steel (A); Corundum-Type oxide (B); Oxidation (C)
资金
- German Research Foundation [UN 341/3-1, RE 1261/19-1, LI 2827/2-1, Inst 275/391-1]
The formation of multilayered oxides on 316 L is reassessed, considering the recently discovered phenomenon of steep concentration gradients in single corundum-type oxide grains after high temperature oxidation. Evidence is shown that the phenomenon applies to oxidation at high and low temperature, with a three-layered Cr-Fe-Cr oxide being preceded by a two-layered Cr-Fe oxide that directly links to observations reported for the native oxide. A coherent growth mechanism is proposed, with the reaction front shifting position depending on the annealing temperature. The absence of spinel-type oxides is discussed considering the Mn distribution.
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