期刊
CONSTRUCTION AND BUILDING MATERIALS
卷 267, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.conbuildmat.2020.120965
关键词
Geopolymer; Fly ash; GGBS; Boroaluminosilicate; Rheology; ATR-FT-IR; MASNMR; Zeta potential
资金
- Department of Science and Technology, the Government of India (GOI), GOI [DST/TDT/WMT/2017 14/03/18]
The study focuses on the use of borax composite sodium silicate activator in geopolymerization, showing advantages in setting time and workability without affecting compressive strength. The borax composite pastes display shear thinning behavior and fit well with the Bingham model. Microstructural changes and spectral analysis reveal specific alterations upon borax addition.
The present study focuses on the use of borax composite sodium silicate activator (B) in place of water glass (S) in the fly ash-GGBS composite (4:1) geopolymerization. The substituent is favoured as it delivers advantages such as increased setting time and workability by mitigating the agglomeration of flocks without affecting the compressive strength of the geopolymer. Microstructural changes of boroaluminosilicate were studied with the help of ATR-FT-IR and MAS NMR. Rheology studies indicated that the borax composite pastes display shear thinning behaviour with low yield stress and fit well with the Bingham model. In-situ ATR-FT-IR spectrum revealed the severing of silica bonds by soluble [BO4] and its incorporation into the silicate backbone resulted in the drop in of Si-O-T asymmetry vibration response. The NMR spectral changes of Si-29, Al-27 and B-11 nuclei environment in geopolymeric tetrahedral network showed that the fraction of [SiO4] and [BO4] increases upon borax addition with the diminished fraction of B-3 non-rings without any specific changes in Al coordination. The tetrahedral boron absorption band in the wave numbers at 1380-1310 cm(-1) and1134 cm(-1) is observed in FT-IR and its configuration is compatible in the reaction product. (C) 2020 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据