期刊
COMBUSTION SCIENCE AND TECHNOLOGY
卷 194, 期 8, 页码 1661-1677出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00102202.2020.1825402
关键词
Coal spontaneous combustion; metal ion; fire extinguishing gel; performance; mechanism
资金
- Shanxi Natural Science Foundation [201801D121265]
A new type of fire-suppression polymer gel with strong stability has been developed to prevent and extinguish mine fires more efficiently. The optimal formula was determined through testing the gelation time and measuring different properties of the gel. The gel was found to have good thermal stability, flowability, and significant effects on suppressing CO emission during coal oxidation.
The spontaneous combustion of coal is one of the main disasters affecting safe production. In order to prevent and extinguish mine fires more efficiently, a new type of fire-suppression polymer gel with strong stability has been developed. The optimal formula was determined by testing the gelation time of different ratios of gel components. The measurement of water retention rate, viscosity and permeability of the gel were also carried out to verify the thermal stability and flowability. The effect of gel on the suppression of CO emission during coal oxidation was tested by the temperature-programming experiments. By the thermogravimetric experiments, the influence of gel on coal activation energy was calculated based on the ignition activation energy theory. FTIR was also introduced to analyze the effect of gel on active groups of coal during coal oxidation. Furthermore, the extinguishing mechanism of the gel was analyzed from forming characteristics. It is proven that the strong stable gel is an excellent fire extinguishing material with the advantages of controllable glue time, good water retention and the obvious effects of sealing.
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